Hi Judith,
Great question! We had a sample of coffee substrate analysed a while back and it proved to be high in high Potassium, Phosphorus, Calcium and Nitrogen. It also had low levels of heavy metals (good to know!). The high calcium and nitrogen are a bonus as these are often added as supplements when growing on straw.
The only problem that coffee has versus straw is the density and particle size being too fine, which is why the addition of 10-20% straw helps to create a nutrient-rich substrate, which also has good structure for the mycelium to prosper.
Best wishes, Adam